Entropy
Entropy is a thermodynamic state variable that quantifies the probabilistic distribution of accesible microstates in a system. The term and the concept are used in diverse fields, from classical thermodynamics (where it was first recognized), to the microscopic description of nature in statistical physics, and the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, and information systems including the transmission of information in telecommunication.
Entropy is central to the second law of thermodynamics, which states that the entropy of an isolated system left to spontaneous evolution cannot decrease with time. As a result, isolated systems evolve toward thermodynamic equilibrium, where the entropy is highest. "High" entropy means that energy is more disordered or dispersed, while "low" entropy means that energy is more ordered or concentrated. A consequence of the second law of thermodynamics is that certain processes are irreversible.
The thermodynamic concept was referred to by Scottish scientist and engineer William Rankine in 1850 with the names thermodynamic function and heat-potential. In 1865, German physicist Rudolf Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of heat to the instantaneous temperature. He initially described it as transformation-content, in German Verwandlungsinhalt, and later coined the term entropy from a Greek word for transformation.
Austrian physicist Ludwig Boltzmann explained entropy as the measure of the number of possible microscopic arrangements or states of individual atoms and molecules of a system that comply with the macroscopic condition of the system. He thereby introduced the concept of statistical disorder and probability distributions into a new field of thermodynamics, called statistical mechanics, and found the link between the microscopic interactions, which fluctuate about an average configuration, to the macroscopically observable behaviour, in the form of a simple logarithmic law, with a proportionality constant, the Boltzmann constant, which has become one of the defining universal constants for the modern International System of Units.
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